Ligand Coupling Reactions Through Hypervalent and Similar Valence-Shell Expanded Intermediates
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Chemical bonding in hypervalent molecules: is the octet rule relevant?
The bonding in a large number of hypervalent molecules of P, As, S, Se, Te, Cl, and Br with the ligands F, Cl, O, CH(3), and CH(2) has been studied using the topological analysis of the electron localization function ELF. This function partitions the electron density of a molecule into core and valence basins and further classifies valence basins according to the number of core basins with whic...
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تاریخ انتشار 2017